Researchers from China and France have reported a molecular stabilization strategy to mitigate light-induced degradation in metal-halide perovskite solar cells. The joint study incorporates a multifunctional hindered amine into the perovskite layer to limit photo-driven chemical decomposition. During illumination, the stabilizer neutralizes superoxide radicals generated in the perovskite film and passivates electronic defects at interfaces and grain boundaries. Together, these effects reduce non-radiative recombination and improve film quality and long-term stability. Using the technique, inverted perovskite solar cells fabricated in ambient conditions achieved a certified power conversion efficiency of 26.74%. Unencapsulated cells preserved more than 95% of their initial efficiency after over 1,000 hours of continuous illumination. The authors state that the strategy is compatible with existing device architectures and scalable fabrication processes.
Hindered amines stabilize perovskite solar cells at improved efficiency
Researchers have shown that hindered amines stabilize perovskite solar cells, enabling efficiencies above 26% while maintaining performance under continuous illumination.
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